Determining Oxidation Numbers

 

Oxidation Number: 
The charge an atom has, or appears to have, when the electrons of the compound are counted in accordance with a set of rules. 
 
 

1.

Free elements are assigned an oxidation state of zero.

2.

The sum of the oxidation states of all that atoms in a species must be equal to the net charge on the species.

3.

The alkali metals (Li, Na, K, Rb, and Cs) in compounds are always assigned an oxidation state of +1.

4.

Fluorine in compounds is always assigned an oxidation state of -1.

5.

The alkaline earth metals (Be, Mg, Ca, Sr, Ba, and Ra) and also Zn and Cd in compounds are always assigned an oxidation state of +2.

6.

Hydrogen in compounds is assigned an oxidation state of +1.

7.

Oxygen in compounds is assigned an oxidation state of -2.

8. Halogen in compounds is assigned an oxidation state of -1.

Application of these rules to a compound must occur in the order given. 

 
This page was last changed on April 07, 2001 15:28

©2001 David A. Grossie, Department of Chemistry, Wright State University, Dayton OH